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Chem exam 2

QuestionAnswer
polar covalent bond covalent bond between 2 atoms with significantly different electronegatives resulting in uneven distribution of electron density
electronegativity the ability of an atom to attract electrons to itself in a covalent bond
increases the electronegativity ______________ across the periodic table
decreases the electronegativity _____________ down the periodic table
nonpolar covalent bond difference in electronegativity is small
ionic bond difference in electronegativity is large
EN 0-0.4 nonpolar covalent
EN 0.4-2 polar covalent
EN 2.0 ionic
dipole moment a measure of the seperation of positive and negative charge in a molecule
distance and magnitude the dipole moment is dependent on ______ and _______
percent ionic character ratio of a bonda actual dipole moment to the dipole moment it would have if the electrons were completely transfered from one atom to another
resonance structure one of two or more avlid lewis structures shown with double headed arrows between them to indicate that the actual structure of the molecule is intermediate between them
resonance hybrid the actual structure of a molecule that is intermediate between 2 or more resonance structures
formal charge fictitious charge assigned to each atom in a lewis structure if all bonding electrons were shared equally
zero the sum of all formal charges in a neutral molecule must be _____
ion the sum of all formal charges in an _____ must equal the charge of the ______
small, large ______ formal charges on indivdula atoms are better than ______ one
electronegative when formal charges cant be avoided, negative formal charges should reside on the most ______ atom
free radicals a molecule or ion with an odd number of electrons in its lewis structure
boron expanded octets happens with _______
third expanded octets happen with the _____ row of the periodic table and beyond
bond energy for a chemical bond, the energy required to break 1 mol of the bond in the gas phase
bond length the average length of a bond between 2 particular atoms
weaker the longer the bond, the ______ the bond
VSPER a theory that allows the prediction of the shapes of molecules based on the idea that electrons repel one another
electron groups a general term for lone pairs, single bonds, multiple bonds and lone electrons in a model
seperation preferred geometry is maximum _________
number, bonding geometry depends on - ______ of electron groups around the central atom - how many _______ vs lone pairs
2 electron groups in linear electron geometry
3 electron groups in trigonal planar electron geometry
4 electro groups in tetrahedral electron geometry
smaller the more lone pairs the bonds get progressively __________
polar any atom with lone pairs is going to be ________
most repulsive lone pair- lone pair
least repulsive bonding pair-bonding pair
chemical change a change that alters the molecular composition of a substance
physical change a change that alters the state of appearance of a substance but not its chemical composition
chemical property a property that a substance displays only by changing the chemical composition
physical property a property that a substance displays without changing chemical composition
chemical equation representation of a chemical reaction; contains an equal number of atoms on either side of the equation
reactants starting substances in a chemical reaction
products substances produced in a chemical reaction
combustion reaction CxHx + O2 ----> CO2 + H20
stoichiometry the numerical relationship between amounts of reactants/products in a balanced chemical equation
mole to mole ratio the key in stoichiometry
solution homogenous mixture of 2 substance
solvent the majority component of a solution
solute the minority component of a solution
aqueous solution water acts as the solvent
dilute solution a solution that contains a very small amount of a solute relative to the amount of the solvent
concentrated solution a solution contains a large amount of solute relative to the amount of solvent
molarity concentration; moles of solution per liter
stock solution a highly concentrated form of a solution used in labs to make less concentrated solutions via dilution
electrolytes a substnace that dilutes in H2O to form solutions that conduct electricity
strong electrolytes a substance that completely dissolves into ions when disolved into water
nonelectrolytes a compound that doesnt dissociate into ions when dissolved in water
acids ionize to form H+ when in water
strong acid an acid that completely ionizes in a solution
weak acids an acid that doesn't completely ionize in H2O
weak electrolytes a substance that doesnt completely ionize in water, only weakly conducts electricity
soluble describes a compound that is able to dissolve a significant extent, usually in h2O
insoluble incapable of dissolving in H2O or is extremely difficuly to dissolve H2O
precipitate a solid, insoluble, ionic compound that forms in seperate fro a solution
precipitate reaction reaction in which a solid, insoluble product forms upon mixing two solutions
Created by: alexiarecinella
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