click below
click below
Normal Size Small Size show me how
CHEM 2 CHPT 15
Equilibrium
| Question | Answer |
|---|---|
| concentrations and ratios are not equal but they are... | constant |
| K>1 | product favored |
| K<1 | reactant favored |
| Kc | equilibrium constant of gaseous and aqueous solutions |
| K uses ___ for formula while Kc uses..... | K: order of reactants Kc: stoichiometry coefficients |
| Product goes in the (for the equation).... | numerator |
| reactant goes in the(for the equation)... | denominator |
| when writing the equation for Kc, what is left out? | solids, pure liquids, and water |
| Kp= | Kc(RT)^delta n |
| R= | .08206 |
| Kp=Kc when... | the total number of moles of a reactant and product are equal |
| Kp is the.... (def) | constant for reactions with only gases and uses partial pressures |
| What is the difference between Q and K | Q is at any conditions while K is at equilibrium |
| Q<k: | System is heading towards equilibrium (more reactant) |
| Q>K: | System is past equilibrium (more product) |
| Kx100 < concentration of reactants | Quadratic equation is not required |
| Kx100 > concentration of reactants | quadratic equation is required |
| K(new) = | K(old)^n |
| K(old)= | K(new)-1 |
| How do you disturb an equilibrium and what is the exception | changing temperature, concentration or changing the volume (exclusive to gases) |
| if the volume doubles, then the concentration is... | cut in half |
| if the volume is cut in half, then the concentration is... | doubled |
| Increasing the volume of a container favors which side of the equilibrium? | the side with the greatest number of moles |
| increasing the temperature of an _____ reaction favors the products | endothermic |
| increasing the temperature of an _____ reaction favors the reactants | exothermic |
| Le chateliers principle | a change in temperature, concentration or volume will cause at system at equilibrium to shift back towards a state of equilibrium |
| What is added to an equation when determining temperature changes on gas phase equilibria? How does this change Q? | energy to the reactant side. Q now includes energy in the denominator (reactant side) |
| As concentration increases, K... | increases |