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Atomic Structure

q/a

QuestionAnswer
Rutherford's atomic model is based on? α-ray scattering experiment
What was the main discovery of Rutherford's model? Nucleus
According to Bohr's model, angular momentum is? mvr = h/2π
According to Bohr, energy of an orbital is given by? E= 13.6 ×z²/n²
According to Bohr, radius of an orbital is given by? r= 0.53×n²/z A°
According to Bohr, velocity of electron in an orbital is given by? v= 2.18×10⁶/n m/s
What is Zeeman effect? Splitting of lines in magnetic field
What is Stark effect? Splitting of lines in electric field
Line spectra(n) was explained by? Bohr
Fine spectra(l) was explained by? Sommerfield
Hyperfine spectra(m) was explained by? Lande
What is the series of hydrogen spectra? Lyman, Balmer, Paschen, Brackett, Pfund, Humphrie
Lyman series lies in which energy region? UV
Balmer series lies in which energy region? Visible
Paschen series lies in which energy region? IR
Practical value of Rydhberg's constant? 109678 /cm
Theoretical value of Rydhberg's constant? 109743 /cm
Wave-mechanical model or Quantum mechanical model was given by? Schrodinger
Wave-mechanical model or Quantum mechanical model is based on? de-Broglie's hypothesis and Heisenberg's uncertainty principle
No of electrons in a shell is given by? 2n²
Difference in energy for consecutive shells _________ with increase in principle quantum no.? decreases
Value of Principle quantum no.(n) is? n---> 0 to ∞
Value of Azimuthal quantum no. (l) is? l---> 0 to (n-1)
Notions for subshells? l=0--> s (sharp lines) l=1--> p (principle lines) l=2--> d (diffused lines) l=3--> f (fundamental lines)
No. of electrons in a subshell is given by? 4l+2
Value of Magnetic quantum no. (m) ranges from? -l to +l
In absence of external field, the orbitals of a subshell are? Degenerate --> subshells are of equal energy Px=Py=Pz
Spin quantum no. was discovered by? Goudsmit and Uhlenbeck
Relative energy of Subshell is given by? E α n+l E α n (if n+l is same)
Afbau's principle states that? Subshell having lower energy is filled up first followed by higher energy subshell
Hund's rule states that? In a particular subshell, there must be one electron in each orbital upto half-filled state
Pauli's exclusion principle states that? no two electrons in an atom can have all four quantum numbers alike
For H-atom, energy of shell depends on? n only
No. of nodes is given by? n-l-1
No. of nodal plane is given by? l
Created by: Mushroomang
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