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Chemistry
Thermodynamics
| Term | Definition |
|---|---|
| Kinetic Energy Equation | KE=1/2mv^2 |
| First Law of Thermodynamics | Energy of Universe is Constant |
| Second Law of Thermodynamics | For any Spontaneous Process, the entropy of the universe increases |
| Third Law of Thermodynamics | The entropy of a perfect crystal at absolute temperature is Zero |
| dE=q+w | q=heat energy (MCdT) w=work energy (-PdV) |
| Specific Heat Capacity | Heat required to raise temp of 1 gram of substance by 1 degree C |
| Molar Heat Capacity | Heat required to raise temp of 1 mole of substance by 1 degree C |
| Calculate quantity of heat released or absorbed | q=MCdT |
| Calculate Work W=-PdV | dV = volume, P=external pressure |
| ΔH = ΔE + PΔV | change in enthalpy/heat |
| If ΔH > 0? | Endothermic |
| if ΔH < 0? | Exothermic |
| Standard enthalpy change | ΔHProducts - ΔHReactants |
| Particles-most freedom to least freedom | Translational, Rotational, Vibrational |
| Gases can be condensed by | Decreasing temperature or increasing pressure |
| A reaction is spontaneous if | ΔG < 0 (Entropy of universe increases) |
| Standard Enthalpy Change for a reaction | ΔSrxn = Sproducts Sreactants |
| Free Energy Changes in Chemical Reactions | ΔGrxn = ΔHrxn TΔSrxn |