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Stack #1420987

QuestionAnswer
1) Identify oxidation. E) both A and B
2) What element is being reduced in the following redox reaction? MnO4⁻ (aq) + H2C2O4(aq) → Mn2+(aq) + CO2(g) C) Mn
3) What element is being oxidized in the following redox reaction? MnO4⁻ (aq) + H2C2O4(aq) → Mn2+(aq) + CO2(g) A) C
4) What element is being oxidized in the following redox reaction? Zn2+(aq) + NH4+(aq) → Zn(s) + NO3⁻(aq) B) N
5) What element is being reduced in the following redox reaction? H2O2(l) + ClO2(aq) → ClO2⁻(aq) + O2(g) C) Cl
6) What element is being oxidized in the following redox reaction? H2O2(l) + ClO2(aq) → ClO2⁻(aq) + O2(g) B) O
7) What element is being oxidized in the following redox reaction? Cr(OH)4⁻(aq) + ClO⁻(aq) → CrO42-(aq) + Cl⁻(aq) A) Cr
8) What element is being reduced in the following redox reaction? Cr(OH)4⁻(aq) + ClO⁻(aq) → CrO42-(aq) + Cl⁻(aq) D) Cl
9) Balance the following redox reaction if it occurs in acidic solution. What are the coefficients in front of H2C2O4 and H2O in the balanced reaction? MnO4⁻ (aq) + H2C2O4(aq) → Mn2+(aq) + CO2(g) A) H2C2O4 = 5, H2O = 8
10) Balance the following redox reaction if it occurs in acidic solution. What are the coefficients in front of H⁺ and Fe3+ in the balanced reaction? Fe2+(aq) + MnO4⁻(aq) → Fe3+(aq) + Mn2+(aq) B) H⁺ = 8, Fe3+ = 5
11) Balance the following redox reaction if it occurs in acidic solution. What are the coefficients in front of Zn and H+ in the balanced reaction? Zn2+(aq) + NH4+(aq) → Zn(s) + NO3⁻(aq) C) Zn = 4, H⁺ = 10
12) Balance the following redox reaction if it occurs in acidic solution. What are the coefficients in front of Cd and Ag+ in the balanced reaction? Cd(s) + Ag+(aq) → Ag(s) + Cd2+(aq) A) Cd = 1, Ag⁺ = 2
13) Balance the following redox reaction if it occurs in basic solution. What are the coefficients in front of Br2 and OH⁻ in the balanced reaction? Br2(l) → BrO3⁻(aq) + Br⁻(aq) D) Br2 = 3, OH⁻ = 6
14) Balance the following redox reaction if it occurs in basic solution. What are the coefficients in front of ClO2 and H2O in the balanced reaction? H2O2(l) + ClO2(aq) → ClO2⁻(aq) + O2(g) E) ClO2 = 2, H2O = 2
15) Balance the following redox reaction if it occurs in basic solution. What are the coefficients in front of Cr(OH)4⁻ and ClO⁻ in the balanced reaction? Cr(OH)4⁻(aq) + ClO⁻(aq) → CrO42-(aq) + Cl⁻(aq) A) Cr(OH)4⁻ = 2, ClO⁻ = 3
16) Balance the following redox reaction if it occurs in basic solution. What are the coefficients in front of Al and F2 in the balanced reaction? Al(s) + F2(g)→ Al3+(aq) + F-(aq) A) Al = 2, F2 = 3
17) Identify the location of oxidation in an electrochemical cell. A) the anode
18) Identify the location of reduction in an electrochemical cell. B) the cathode
19) Define a salt bridge. E) A pathway by which counterions can flow between the half-cells without the solutions in the half-cell totally mixing.
20) Determine the redox reaction represented by the following cell notation. Mg(s) ∣ Mg2+(aq)  Cu2+(aq) ∣ Cu(s) B) Mg(s) + Cu2+(aq) → Cu(s) + Mg2+(aq)
21) Determine the cell notation for the redox reaction given below. Sn(s) + 2 Ag⁺(aq) → Sn2+(aq) + 2 Ag(s) C) Sn(s) ∣ Sn2+(aq)  Ag+(aq) ∣ Ag(s)
22) Determine the cell notation for the redox reaction given below. Pb(s) + 2 H⁺(aq) → Pb2+(aq) + H2(g) D) Pb(s) ∣ Pb2+(aq)  H+(aq) ∣ H2(g) ∣ Pt
23) Determine the cell notation for the redox reaction given below. 3 Cl2(g) + 2 Fe(s) → 6 Cl⁻(aq) + 2 Fe3+(aq) E) Fe(s) ∣ Fe3+(aq)  Cl2(g) ∣ Cl⁻(aq) ∣ Pt
24) What is the reducing agent in the redox reaction represented by the following cell notation? Ni(s) ∣ Ni2+(aq)  Ag+(aq) ∣ Ag(s) A) Ni(s)
25) What is the oxidizing agent in the redox reaction represented by the following cell notation? Ni(s) ∣ Ni2+(aq)  Ag+(aq) ∣ Ag(s) C) Ag+(aq)
26) What is the oxidizing agent in the redox reaction represented by the following cell notation? Sn(s) ∣ Sn2+(aq)  Ag+(aq) ∣ Ag(s) B) Ag+(aq)
27) What is the reducing agent in the redox reaction represented by the following cell notation? Sn(s) ∣ Sn2+(aq)  Ag+(aq) ∣ Ag(s) A) Sn(s)
28) What is undergoing reduction in the redox reaction represented by the following cell notation? Fe(s) ∣ Fe3+(aq)  Cl2(g) ∣ Cl⁻(aq) ∣ Pt C) Cl2(g)
29) What is undergoing oxidation in the redox reaction represented by the following cell notation? Fe(s) ∣ Fe3+(aq)  Cl2(g) ∣ Cl⁻(aq) ∣ Pt A) Fe(s)
30) What is undergoing oxidation in the redox reaction represented by the following cell notation? Pb(s) ∣ Pb2+(aq)  H+(aq) ∣ H2(g) ∣ Pt D) Pb(s)
31) What is undergoing reduction in the redox reaction represented by the following cell notation? Pb(s) ∣ Pb2+(aq)  H+(aq) ∣ H2(g) ∣ Pt B) H+(aq)
32) What statement is NOT true about standard electrode potentials? D) E°cell is the difference in voltage between the anode and the cathode.
33) Which of the following is the strongest reducing agent? D) Cr(s) E) Li(s) C) Mg(s)
34) Which of the following is the weakest oxidizing agent? D) Cr(s D) I2(s)
1) Q = 1 C) Ecell = E°cell
2) Q > K A) Ecell < 0
37) Which of the following is the weakest reducing agent? B) Zn(s) B) Au3+(aq)
38) Which of the following is the strongest oxidizing agent? E) MnO4⁻(aq) B) Au3+(aq) A) H2O2(aq)
3) Q < K D) Ecell > 0
4) ΔG° < 0 B) E°cell > 0
5) ΔG° > 0 F) E°cell < 0
6) Q = K E) Ecell = 0
43) 3 Cl2(g) + 2 Fe(s) → 6 Cl⁻(aq) + 2 Fe3+(aq) Cl2(g) + 2 e⁻ → 2 Cl⁻(aq) E° = +1.36 V Fe3+(aq) + 3 e⁻ → Fe(s) E° = -0.04 V E) +1.40 V
44) Pb(s) + Br2(l) → Pb2+(aq) + 2 Br⁻(aq) Pb2+(aq) + 2 e⁻ → Pb(s) E° = -0.13 V Br2(l) + 2 e⁻ → 2 Br⁻(aq) E° = +1.07 V A) +1.20 V
45) Sn(s) + 2 Ag⁺(aq) → Sn2+(aq) + 2 Ag(s) Sn2+(aq) + 2 e⁻ → Sn(s) E° = -0.14 V Ag⁺(aq) + e⁻ → Ag(s) E° = +0.80 V B) +0.94 V
46) Mg(s) + Cu2+(aq) → Cu(s) + Mg2+(aq) Mg2+(aq) + 2 e⁻ → Mg(s) E° = -2.38 V Cu2+(aq) + 2 e⁻ → Cu(s) E° = +0.34 V C) +2.72 V
47) 2 K(s) + I2(s) → 2 K⁺(aq) + 2 I⁻(aq) K+(aq) + e⁻ → K (s) E° = -2.93 V I2(s) + 2 e⁻ → 2 I⁻(aq) E° = +0.54 V D) +3.47 V
48) Determine which of the following pairs of reactants will result in a spontaneous reaction at 25°C. D) Fe3+(aq) + Ni(s)
49) Determine which of the following pairs of reactants will result in a spontaneous reaction at 25°C. A) Sn4+(aq) + Mg(s)
50) Determine which of the following pairs of reactants will result in a spontaneous reaction at 25°C. B) Ca(s) + Mg2+(aq)
51) Which of the following metals will dissolve in nitric acid but not hydrochloric? C) Cu
52) Which of the following metals will dissolve in nitric acid but not hydrochloric? D) Ag
53) Which of the following metals will dissolve in HCl? E) all of the above
54) Which of the following metals will not dissolve in nitric acid or hydrochloric acid? D) Au
55) Which of the following metals will not dissolve in nitric acid or hydrochloric acid? E) none of the above
56) Identify the characteristics of a spontaneous reaction. D) all of the above
57) How many electrons are transferred in the following reaction? (The reaction is unbalanced.) Mg(s) + Al3+(aq) → Al(s) + Mg2+(aq) A) 6
58) How many electrons are transferred in the following reaction? (The reaction is unbalanced.) Fe2+(aq) + K(s) → Fe(s) + K+(aq) B) 2
59) How many electrons are transferred in the following reaction? (The reaction is unbalanced.) I2(s) + Fe(s) → Fe3+(aq) + I⁻(aq) C) 6
60) Which of the following reactions would have the smallest value of K at 298 K? C) A + B → 2 C; E°cell = -0.030 V
61) Use the tabulated half-cell potentials to calculate ΔG° for the following balanced redox reaction. Pb2+(aq) + Cu(s) → Pb(s) + Cu2+(aq) D) +91 kJ
62) Use the tabulated half-cell potentials to calculate ΔG° for the following balanced redox reaction. 3 I2(s) + 2 Fe(s) → 2 Fe3+(aq) + 6 I⁻(aq) E) -3.3 x 102 kJ
63) Use the tabulated half-cell potentials to calculate ΔG° for the following redox reaction. 2 Al(s) + 3 Mg2+(aq) → 2 Al3+(aq) + 3 Mg(s) A) +4.1 x 102 kJ
64) Which of the following reactions would be the most spontaneous at 298 K? D) A + B → C; E°cell = +1.22 V
65) Use the tabulated half-cell potentials to calculate the equilibrium constant (K) for the following balanced redox reaction at 25°C. 2 Al(s) + 3 Mg2+(aq) → 2 Al3+(aq) + 3 Mg(s) C) 1.1 x 10-72
66) Use the tabulated half-cell potentials to calculate the equilibrium constant (K) for the following balanced redox reaction at 25°C. 3 I2(s) + 2 Fe(s) → 2 Fe3+(aq) + 6 I⁻(aq) C) 2.4 × 1058
67) Use the tabulated half-cell potentials to calculate the equilibrium constant (K) for the following balanced redox reaction at 25°C. Pb2+(aq) + Cu(s) → Pb(s) + Cu2+(aq) D) 1.3 × 10-16
68) Calculate the cell potential for the following reaction that takes place in an electrochemical cell at 25°C. Sn(s) ∣ Sn2+(aq, 1.8 M)  Ag+(aq, 0.055 M) ∣ Ag(s) E) +0.86 V
69) Calculate the cell potential for the following reaction that takes place in an electrochemical cell at 25°C. Sn(s) ∣ Sn2+(aq, 0.022 M)  Ag+(aq, 2.7 M) ∣ Ag(s) A) +1.01 V
70) Calculate the cell potential for the following reaction that takes place in an electrochemical cell at 25°C. Mg(s) ∣ Mg2+(aq, 2.74 M)  Cu2+(aq, 0.0033 M) ∣ Cu(s) B) +2.62 V
71) Calculate the cell potential for the following reaction that takes place in an electrochemical cell at 25°C. Fe(s) ∣ Fe3+(aq, 0.0011 M)  Fe3+(aq, 2.33 M) ∣ Fe(s) A) +0.066 V
72) Calculate the cell potential for the following reaction that takes place in an electrochemical cell at 25°C. Cu(s) ∣ Cu2+(aq, 0.0032 M)  Cu2+(aq, 4.48 M) ∣ Cu(s) B) +0.093 V
73) Calculate the cell potential for the following reaction that takes place in an electrochemical cell at 25°C. Al(s) ∣ Al3+(aq, 0.115 M)  Al3+(aq, 3.89 M) ∣ Al(s) E) +0.030 V
74) Identify the battery that is in most automobiles. C) lead-acid storage battery
75) Identify the battery that is used as a common flashlight battery. A) dry-cell battery
76) Identify the components of a fuel cell. C) hydrogen-oxygen
77) Identify the battery type that has a high overcharge tolerance. D) lead storage
78) What is the reaction at the anode in a breathalyzer? A) Ethanol is oxidized to acetic acid.
79) What is the reaction at the cathode in a breathalyzer? C) Oxygen is reduced.
80) Describe how water can be a good conductor of current. C) add salt
81) What mass of silver can be plated onto an object in 33.5 minutes at 8.70 A of current? Ag⁺(aq) + e⁻ → Ag(s) A) 19.6 g
82) What mass of aluminum can be plated onto an object in 755 minutes at 5.80 A of current? B) 24.5 g
83) Nickel can be plated from aqueous solution according to the following half reaction. How long would it take (in min) to plate 29.6 g of nickel at 4.7 A? Ni2+(aq) + 2 e⁻ → Ni(s) C) 3.5 × 102 min
84) Identify a component in the formation of rust. D) all of the above
85) Predict the species that will be reduced first if the following mixture of molten salts undergoes electrolysis. Na+, Ca2+, Cl⁻, Br⁻, F⁻ A) Na⁺
86) Predict the species that will be reduced first if the following mixture of molten salts undergoes electrolysis. Zn2+, Fe3+, Mg2+, Br-, I- D) Fe3+
87) Predict the species that will be oxidized first if the following mixture of molten salts undergoes electrolysis. Cu2+, Mg2+, Cl⁻, Br⁻, F⁻ E) Br⁻
1) What is the reduction half-reaction for the following overall galvanic cell reaction? Co2+(aq) + 2 Ag(s) → Co(s) + 2 Ag+(aq) C) Co2+(aq) + 2 e- → Co(s)
2) What is the shorthand notation that represents the following galvanic cell reaction? Pb(s) + Cu(NO3)2(aq) → Pb(NO3)2(aq) + Cu(s) A) Pb(s) ∣ Pb2+(aq) ∣∣ Cu2+(aq) ∣ Cu(s)
3) What is the shorthand notation that represents the following galvanic cell reaction? 2 Fe2+(aq) + F2(g) → 2 Fe3+(aq) + 2 F-(aq) D) Pt(s) ∣ Fe2+(aq), Fe3+(aq) ∣∣ F2(g) ∣ F-(aq) ∣ C(s)
4) For the galvanic cell reaction, expressed below using shorthand notation, what half-reaction occurs at the cathode? Zn(s) ∣ Zn2+(aq) ∣∣ Ni2+(aq) ∣ Ni(s) D) Ni2+(aq) + 2 e- → Ni(s)
5) What is the balanced chemical equation for the galvanic cell reaction expressed using shorthand notation below? Al(s) ∣ Al3+(aq) ∣∣ Fe2+(aq) ∣ Fe(s) A) 2 Al(s) + 3 Fe2+(aq) → 2 Al3+(aq) + 3 Fe(s)
6) What is the balanced equation for the galvanic cell reaction expressed using shorthand notation below?. Ni(s) ∣ Ni2+(aq) ∣∣ Cl2(g) ∣ Cl-(aq) ∣ C(s) B) Ni(s) + Cl2(g) → Ni2+(aq) + 2 Cl-(aq)
7) A galvanic cell consists of a Ni2+/ Ni half-cell and a standard hydrogen electrode. If the Ni2+/ Ni half-cell standard cell functions as the anode, and the standard cell potential is 0.26 V, what is the standard A) - 0.26 V
8) A galvanic cell consists of one half-cell that contains Ag(s) and Ag+(aq), and one half-cell that contains Cu(s) and Cu2+(aq). What species are produced at the electrodes under standard conditions? Ag+(aq) + e- → Ag(s) E° = +0.80 V Cu2+(aq) + 2 B) Ag(s) is formed at the cathode, and Cu2+(aq) is formed at the anode.
9) Consider the following standard reduction potentials, Ni2+(aq) + 2 e- → Ni(s) E° = - 0.26 V I2(s) + 2 e- → 2 I-(aq) E° = +0.54 V Under standard conditions, B) I2(s) is a stronger oxidizing agent than Ni2+(aq) and Ni(s) is a stronger reducing agent than I-(aq).
10) Consider the galvanic cell, Zn(s) ∣ Zn2+(aq) ∣∣ Pb2+(aq) ∣ Pb(s). Which one of the following changes to the cell would cause the cell potential to increase (i.e., become more positive)? B) increase the [ Pb2+] concentration
11) Based on the following information, Cl2(g) + 2 e- → 2 Cl-(aq) E° = + 1.36 V Mg2+(aq) + 2 e- → 2 Mg(s) E° = -2.37 V which of the following chemical species is the strongest reducing agent? D) Mg(s)
12) Using the following standard reduction potentials, Fe3+(aq) + e- →Fe2+(aq) E° = +0. 77 V Ni2+(aq) + 2 e- →Ni(s) E° = -0.23 V calculate the standard cell potential for the galvanic cell reaction given below, and determine whether or not this r A) E° = - 1.00 V, nonspontaneous
13) The gas OF2 can be produced from the electrolysis of an aqueous solution of KF, as shown in the equation below. OF2(g) + 2 H+(aq) + 4 e- → H2O(l) + 2 F-(aq) E° = +2.15 V Using the given standard reduction potential, calculate the amount of OF2 that A) 6.48 g of OF2 at the anode.
14) Given that E°red = -1.66 V for Al3+/ Al at 25°C, find E° and E for the concentration cell expressed using shorthand notation below. Al(s) ∣ Al3+(1.0 × 10-5 M) ∣∣ Al3+(0.100 M) ∣ Al(s) B) E° = 0.00 V and E = +0.12 V
15) The standard cell potential (E°) of a voltaic cell constructed using the cell reaction below is 0.76 V: Zn (s) + 2H+ (aq) → Zn2+ (aq) + H2 (g) With PH2 = 1.0 atm and [Zn2+] = 1.0 M, the cell potential is 0.66 V. The concentration of H+ in th A) 2.0 × 10-2
16) A voltaic cell is constructed with two silver-silver chloride electrodes, where the half-reaction is AgCl (s) + e- → Ag (s) + Cl- (aq) E° = +0.222 V The concentrations of chloride ion in the two compartments are 0.0222 M and 2.22 M, respect B) 0.118
17) A voltaic cell is constructed with two Zn2+-Zn electrodes, where the half-reaction is Zn2+ + 2e- → Zn (s) E° = -0.763 V The concentrations of zinc ion in the two compartments are 5.50 M and 1.11 × 10-2 M, respectively. The cell emf is _____ C) 0.0798
18) The standard emf for the cell using the overall cell reaction below is +2.20 V: 2 Al (s) + 3 I2 (s) → 2 Al3+ (aq) + 6 I- (aq) The emf generated by the cell when [Al3+] = 4.5 × 10-3 M and [I-] = 0.15 M is __________ V. B) 2.32
19) The standard emf for the cell using the overall cell reaction below is +0.48 V: Zn (s) + Ni2+ (aq) → Zn2+ (aq) + Ni (s) The emf generated by the cell when [Ni2+] = 2.50 M and [Zn2+] = 0.100 M is __________ V. C) 0.52
20) The electrolysis of molten AlCl3 for 3.25 hr with an electrical current of 15.0 A produces __________ g of aluminum metal. D) 16.4
21) For a galvanic cell that uses the following two half-reactions, Cr2O72-(aq) + 14 H+(aq) + 6 e- → 2 Cr3+(aq) + 7 H2O(l) Pb(s) → Pb2+(aq) + 2 e- how many moles of Pb(s) are oxidized by three mol es of Cr2O72-? C) 9
22) How many kilowatt-hours of electricity are used to produce 3.00 kg of magnesium in the electrolysis of molten MgCl2 with an applied emf of 4.50 V? D) 29.8
23) The most useful ore of aluminum is bauxite, in which Al is present as hydrated oxides, Al2O3 · xH2O. The number of kilowatt-hours of electricity required to produce 4.00 kg of aluminum from electrolysis of compounds from bauxite is __________ when the E) 59.6
24) How many seconds are required to produce 4.00 g of aluminum metal from the electrolysis of molten AlCl3 with an electrical current of 12.0 A? E) 3.57 × 103
25) How many grams of chromium metal are plated out when a constant current of 8.00 A is passed through an aqueous solution containing Cr3+ ions for 320. minutes? A) 27.6 g
26) How many grams of nickel metal are plated out when a constant current of 15.0 A is passed through aqueous NiCl2 for 60.0 minutes? B) 16.4 g
27) How long must a constant current of 50.0 A be passed through an electrolytic cell containing aqueous Cu2+ ions to produce 5.00 moles of copper metal? D) 5.36 hours
28) The town of Natrium, West Virginia, derives its name from the sodium produced in the electrolysis of molten sodium chloride (NaCl) mined from ancient salt deposits. The number of kilowatt-hours of electricity required to produce 4.60 kg of metallic s A) 24.1
Created by: isha2326
 

 



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