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Chemical Equilibrium Review

Quiz yourself by thinking what should be in each of the black spaces below before clicking on it to display the answer.
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Question
Answer
15.1) What is the point at which the concentrations of all species are constant?   Chemical equilibrium  
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15.1) In a rate law, are the concentrations of just reactants, just products, or both included?   Reactants  
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15.1) What type of equilibrium exists when the rates of the forward and reverse reactions are equal?   Dynamic  
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15.2) What is K subscript c?   The equilibrium constant in terms of concentration  
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15.2) What is K subscript p?   The equilibrium constant in terms of pressure  
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15.2) In an equilibrium-constant expression, is K subscript c equal to the concentration of reactants over the the concentration of products?   No, concentration of products over concentration of reactants  
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15.2) Which phases of matter are eliminated from equilibrium-constant expressions?   Solids and liquids  
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15.2) In the general expression relating K subscript c and K subscript p, how is the change in n calculated?   Moles of gaseous product - moles of gaseous reactant  
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15.3) If K >> 1, do products or reactants dominate at equilibrium?   Products  
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15.3) If K << 1, do products or reactants dominate at equilibrium?   Reactants  
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15.3) How is the equilibrium constant for the forward reaction related to the equilibrium constant for the reverse reaction?   Reciprocals  
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15.3) How is the equilibrium constant for a net reaction of two or more steps determined?   Product of K's for individual steps  
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15.4) What type of equilibria has all reactants and products present in the same phase?   Homogeneous  
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15.4) What type of equilibria has products and reactants present in different phases?   Heterogeneous  
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15.6) What is used to determine the value of the equilibrium expression, when the system is not at equilibrium?   Q, the reaction quotient  
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15.6) How are Q and K related when the system is at equilibrium?   Q = K  
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15.6) How are Q and K related when the forward reaction must occur to reach equilibrium?   Q < K  
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15.6) How are Q and K related when the reverse reaction must occur to reach equilibrium?   Q > K  
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15.7) What is the term for a system that will shift its equilibrium position to counteract the effects of a disturbance?   Le Chatelier's Principle  
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15.7) What disturbances does Le Chatelier's Principle include?   Change in: temperature, pressure, concentration  
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15.7) If you remove product from a system at equilibrium, which way does the reaction proceed?   Toward the product  
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15.7) If the pressure is increased in a gaseous system, which way does the reaction proceed?   Toward the direction with fewer moles  
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15.7) What happens to K when increasing the temperature of an endothermic reaction?   Increases  
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15.7) What happens to K when increasing the temperature of an exothermic reaction?   Decreases  
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15.7) How does a catalyst speed up a reaction?   Lowers activation energy  
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