Ochem substitution and Elimination
Quiz yourself by thinking what should be in
each of the black spaces below before clicking
on it to display the answer.
Help!
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| aprotic solvent | A solvent that does not have Hydrogen, therefore no H-bonding will occur.
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| aprotic polar solvent | solvents that lack an acidic hydrogen these compounds have high dielectric constants and high dipole moments. Great for Sn2 reactions. Examples: DMF, HMPA, DMSO
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| base | A molecule who's interactions are determined by acid base equilibrium
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| basicity | Strength of a base: determined by size and electronegativity
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| back-side attack | When a nucleophile interacts with a reactant that is sp3 hybridized it must approach from the opposite side of the leaving group in order for enough orbital overlap to occur for bonding
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| bifunctional molecule |
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| bimolecular |
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| complete racemization |
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| dielectric constant |
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| elimination reaction |
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| first-order reaction |
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| intermolecular reaction |
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| intimate ion pair |
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| intramolecular reaction |
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| inversion of configuration |
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| ion-dipole interaction |
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| kinetics |
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| leaving group |
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| nucleophile |
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| nucleophilicity |
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| nucleophilic substitution reaction |
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| partial racemization |
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| protic solvent |
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| rate constatnt |
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| rate law |
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| second-order reaction |
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| Sn1 reaction |
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| Sn2 reaction |
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| solvolysis |
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| steric effects |
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| steric hindrance |
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| substitution reaction |
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| unimolecular |
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Created by:
Ciankee
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