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Chem 111- Unit 4

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Question
Answer
molecular polarity   a net imbalance of charge over an entire molecule  
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polarity depends on   bonds, shape, orientation  
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6 intermolecular forces (strongest -> weakest)   1) ion-dipole 2) H-bonds 3) Dipole-dipole 4) Ion-induced dipole 5) Dipole-induced dipole 6) Dispersion  
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Polarity and boiling point   As polarity increases, so does boiling (& melting) point  
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particle motion assumption (2) (kinetic molecular theory)   -constant, random, straight-line motion (until collision) -distribution of speeds  
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particle collisions assumption (3) (kinetic molecular theory)   -collisions exchange kinetic energy -total kinetic energy is constant (Ek) -between collisions, molecules don't influence each other  
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particle volume assumption (3) (kinetic molecular theory)   -large collection of molecules -particles have mass but no volume -volume of gas=volume of container  
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at the temperature b/w substances...   Ek is constant  
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___mm Hg (or torr) = 1 atm   760  
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P is prop. to   (n)(T)/(V)  
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Dalton's law of partial pressures   in a mixture, the total pressure = sum of pressures of gases  
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exception to ideal gas law   at high pressure, IM forces lower the pressure  
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Molarity   Moles of solute/L solution  
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polarizability (pattern)   the more dispersion, the more susceptible an atom is to induced polarization (larger atoms)  
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does NOT change during reactions (3)   mass, #atoms, types of atoms,  
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DOES change during reactions (4)   types of molecules, # of bonds, total moles, pressure  
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electrolyte   charged particles that can move (& conduct electricity)  
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molecular speeds of heavier particles   steep graphs  
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during H-bonding, NOF need ____   lone pairs!  
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polarizability (definition)   how easily an electron cloud can be distorted  
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dispersion force (definition)   the intermolecular force responsible for the condensed states of nonpolar substances  
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molecular speeds of lighter particles   long graphs  
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