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Chem 2045 test 2

Quiz yourself by thinking what should be in each of the black spaces below before clicking on it to display the answer.
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Question
Answer
Maxwell   Theory of EM waves  
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Thomson   Plum pudding model  
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Bohr   Planetary model  
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Lenard   Studied the photoelectric effect  
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Hertz   Discovered the photoelectric effect  
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Heisenberg   Uncertainty principle  
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Debroglie   Proposed matter waves  
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Sommerfield   Elliptical orbits in Bohr model  
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Schroedinger   Wave mechanics  
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Foucault   Speed of light in air> water  
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Becquerel   Discovered radioactivity  
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Davisson, Germer   Exp. confirmed wave side of electron  
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Newton   Earliest particles theory of light  
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Einstein   Explained the photoelectric effect  
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Huygens   Earliest wave theory of light  
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Planck   Introduced the idea of Quanta  
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Pauli   Exclusion principle  
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Dirac   Most abstract quantum theory  
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Rutherford   Nuclear model of the atom  
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Young   Interference of light  
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1st E.A.   Energy change when a gaseous atom gains an electron  
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Quantum stability   Half and completely filled sublevels are extra stable  
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Dispersion   Different λ bend at different angles  
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Metastable state   Excited state with long lifetime  
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Wavelength   Peak to peak distance in a wave  
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Phosphorescence   Absorption of high energy with a delayed release of lower energy  
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Quantum   Particles of energy  
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Fluoresence   Absorption of high energy followed by immediate release of lower energy  
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Frequency   # waves passing a given pt in one S  
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Relativistic effect   Energy change when a gaseous atom gains an electron  
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Ground state   All e- are in lowest possible energy level  
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Valence e-   S and P electrons in the outer level  
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Isoelectonic   Having the same e- configurations  
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Ionization energy   Energy required to remove outer e-  
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Excited state   One or more e- are not in the lowest possible energy level  
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Order of discovery   e-, p, n  
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Gold Foil experiment   1. Alpha particles were shot into a gold foil 2. Results were not exactly as expected 3. It was performed in 1909  
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Discovered by Newton   Continuous Spectrum  
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Magnetic splitting of spectral lines   Zeeman effect  
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Planck's quantum idea   Used to explain blackbody radiation  
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Einstein's explanation of the photoelectric effect   Extended the quantum idea to all forms of energy  
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Bohr principle of complementarity states   Light sometimes behaves as a wave, sometimes as a particle, but never both at the same time  
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Original Bohr model   The electron can jump from one orbit to another  
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The fully modified Bohr model failed in which way?   Did not work for multi electron atoms  
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The fully modified Bohr model included   1. 4 quantum numbers 2. Selection rules 3.Elliptical orbits  
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Heisenberg uncertainty principle   Allows for violation of matter energy conservation  
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For quantum teleportation to occur   An end-run must be done around the uncertainty principle  
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The modern picture of empty space is that it   Exists as a quantum foam  
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Have the smallest I.E. value   Na 1+  
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The 1st I.E. of P is abnormally large because   P has half filled p sublevel  
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Einstein was against Bohr's interpretation of quantum theory for each of the following reasons   1. "God does not play dice with the universe" 2. Was against copenhagen interpretation 3. Quantum theory is incomplete are hidden variables  
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In a many electron atom, n determines what about an orbital   Energy and size  
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In a many electron atom what does, I, the orbital quantum #, determine about an orbital   Energy and shape  
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The max # of electron in the n=3 level is   18  
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The max# of electron in the I=3 sublevel is   14  
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Configuration of Cu   1s^2, 2s^2, 2p^6, 3s^2, 3p^6, 4s^1, 3d^10  
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In a many electron atom, n determines what about an orbital   Energy and size  
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In a many electron atom, n determines what about an orbital   Energy and size  
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In a many electron atom what does, I, the orbital quantum #, determine about an orbital   Energy and shape  
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The max # of electron in the n=3 level is   18  
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The max# of electron in the I=3 sublevel is   14  
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Configuration of Cu   1s^2, 2s^2, 2p^6, 3s^2, 3p^6, 4s^1, 3d^10  
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Which is true concerning the n+1 rule in determining the sublevel with the lower energy   It will have lower n+I value and If n+I values are equal then it will have lower n value  
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Belongs to the Lyman series   4->1  
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Compare Sr, Vs, Ca As to metallic nature   Sr is more metallic  
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Interpretation of the quantum theory that involves multiple universes   Many Worlds  
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Even though atomic size gradually decreases across a period for transition elements, Hg is actually larger than Os because   1. Expansion of 5d orbital 2.e- repulsions 3.Relativistic effects  
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Densest element   Osmium  
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The unusual properties of gold can be explained by   The Relativistic effect  
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Not an unusual property of gold   Highly reactive  
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Not one of the coinage metals   Cr  
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Pair of metals have an abnormal yellow color   Cu, Au  
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Correct short form configuration 77 Ir   [Xe] 6s^2 4f^14 5d^7  
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Correct short form configuration for 97 Bk   [Rn] 7s^2 5f^8 6d^1  
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Correct electron configuration of 62 Sm   1s^2, 2s^2, 2p^6, 3s^2, 3p^6, 4s^2, 3d^10, 4p^6, 5s^2, 4d^10, 5p^6, 6s^2, 4f^5, 5d^1  
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