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BioChem1100.tri-c

Chap10.timberlake

QuestionAnswer
arrhenius -theory of acids (4) 1. Taste sour (Latin "acidus" sour) 2. produce hydrogen ions (H+) 3. Change blue litmus to red 4. Corrode some metals
Name acids(minus1) - Hydrogen chloride (HCl) Dissolves in water to form HCl(aq) - hydrochloric acid
HBr(minus1) (polyatomic) Bromide hydrobromic acid
HNO3(Minus1) - Nitrate Nitrous acid
SO4(minus2) Sulfate H2SO4-sulfuric acid
SO3(minus2) sulfite H2SO3 sulfurous acid
Hydronium ion H3O+ Ion formed by the attraction of a proton (H+) to an H2O molecule
How does hydrochloric acid form? HCl HCl = H2O form H3O+ and CL(minus1)
How does ammonia form? NH3 NH3 + H2O forms NH4+ and OH(minus1) - Ammonium ions & hydroxide ions in equilibrium - WATER ACTS AS ACID by donating proton
Reaction where water acts as acid Formation of ammonium & hydroxide
Bronsted-Lowry theory Reaction between acid and base involves a PROTON transfer
Arrhenius theory Acids are substances that produce hydrogen ions (H+) when dissolved in water
amphoteric Can act as both an acid and a base
When does water accept H+? When it reacts with a STRONGER acid
When does water donate H+ When it reacts with a STRONGER BASE
Calculate pH Enter [H3O+] value; presse EE; enter exponent; then enter - sign; press log key; change sign; round to scientific figures
What is VALUE of Kw (for all solutions) Kw=[H3O+] x [OH-] = 1.00 x 10(neg14)
How do you find [OH-}? 1.00 x 10(neg14) Divided by value of [H3O+] will equal [OH-]
Hydronium ion H3O
Bronsted-Lowry acid Donates a proton [H+]; thereby becomes H-
Bronsted-Lowry base Accept a proton; thereby become positive
Water can be an acid or a base True
When does water donate H+ When it reacts with a stronger base
When does water accept H+ When it reacts with a stronger acid
STrong acids Perchloric (HCLO4); sulfuric (H2SO4); hydroidic (HI); Hydrochloric (HCL); nitric acid (HNO3)
Identify Conjugate Acid-Base Pairs HBR(aq) + NH3(aq) ---- Br(neg) + NH4+ (positive) [Br is conjugate base and NH4+ is the conjugate acid
Do strong acids dissociate (separates into ions in water) Yes, a strong acid dissociates completely
Do strong bases dissociate (separate into ions in water) Yes, a strong base dissociates complete
Example of a strong base KOH - solution consists of K+ and OH(neg) Write equation with ONE arrow: KOH(s) --------(addH2O) K+(aq) + OH(neg)(aq)
What is equation for acid dissociation constant? K(asub) = [H3O+][A(neg)/[HA}
Acid ionization constant - equation same as acid dissociation constantK(asub) = [H3O+][A(neg)/[HA}
What is ionization of water? Amphoteric - water can be an acid or base
What is ion-product constant of water? In pure water, the transfer of a proton between two water molecules produce equal number of HcO+ and OH(neg)
Ion-product constant of water - equation Kw = [H3O+] x [OH(neg)]
Neutral solution - pure water [H3O+] and [OH(neg)} are equal (however, most solutions are not neutral)
What does the pH scale represent? A number between 0 and 14 represent the [H3O+]
A pH scale less than 7 is Acid (the smaller the number, the stronger the acid)
pH = 7 Neutral solution
pH is greater than 7 This is a basic solution
pH - equation pH = -log[H3O+]
Example of a strong base (home product) Drano - NaOH (lye) pH value = 14
Active metals Potassium, sodium, calcium, magnesium, aluminum, zinc, iron & tin - react with acids to produce hydrogen gas (H2)
Acids, carbonates & bicarbonates Strong acids added to a carbonates (or bicarbonates) produce bubbles of carbon dioxide gas, a salt, and water (ingredient in acid rain)
Neutralization - between acid & base Neutralization is a reaction between an acid & base to produce a salt & water - cation in the salt comes from the base - the anion comes from the acid
Neutralization of a base (ex.) HCl(aq) = NaOH (aq) ----- NaCL(aq) this is the salt and H2O water
Titration The addition of BASE to an acid sample to determine the concentration of the acid
Name acid with H and a non metal Use prefix "hydro" and end with ic acid Ex. Hydrochloric acid
Name acid with H and polyatomic ion Change end of polyatomic ion from "ate" or "ite" to "ic acid" or "ous acid" Ex. ClO3 is chlorate - becomes HClO3 - chloric acid
Name base Bases with OH- ions are named as "hydroxide" of metal Ex. Al(OH)3 aluminum hydroxide
what produces H+ in aqueous solutions (acid or base?) Acid
What produces H- in aqueous solutions Base
Adding an acid to pure water increases ________ and causes it to _________ and decreases _________ Adding an acid to pure water increases [H3O+] and increases the concentration to more than 1.0 x 10neg7 power and decreases the [OH(neg)]
Adding a base to pure water increases _________ and causes it to _____________ and decreases the ___________ Adding a base to pure water increases the [OH-] and causes its concentration to increase above 1.0 x 10-7 and decreases the [H3O+]
titration process uses an _______________ to measure the concentration of a solution an INDICATOR will change color to show the concentration
End point - what does this mean in titration? It means the solution has reacted with the indicator & can be compared to the test strips (or other media)
Strong acids & strong bases - what will form neutral salts? BASES -"Lippy (Li) Kissy (K) Salty (Na) Calcium (Ca)Maggy (Mg) Syrup (SR)Barium combine "Clorie" (Cl) Boring (Br) Iodine (I) and "Nitie" Nitric acid
What is pH range in blood? Blood MUST be pH 7.35-7.45 or health is threatened
Created by: walterina4327
 

 



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