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DENTAL MATERIALS

POLYMERS

QuestionAnswer
The use of polymers was made possible by -----when he created vulcanized rubber. Charles Goodyear
15-20 years later the material was introduced as a denture base called ----- or ------- Ebonite or Vulcanite
Large long molecules formed by smaller molecules called monomers. Polymers
When small molecules are different but compatible they are called ------- copolymer
Chemical reaction that links the monomers together is called polymerization
Polymers are plastics such as acrylics and plexi-glass
Long linear chains of molecules that can be heated, molded or shaped and may be remelted and reprocessed. SOFT and FLEXIBLE Thermoplastic polymers
Cross-linked chains of molecules that cannot be heated or remolded, a chemical change takes place and they need to be in their final shape when polymerization takes place. Thermoset polymers.
Denture bases, acrylic teeth and retainers are examples of what type of polymer? Thermoset
Polymerization of acrylics are referred to as Addition Polymerization
Most common form of polymerization Addition polymerization
Composite resins, cements, sealants, and adhesives all set by way of ----------- Addition polymerization
What are acrylic resins used for? temporary crowns, custom trays, and base plate for dentures.
Most commonly used resin cold cure or chemically cured
Liquid: MONOMER Methyl Methacrylate
What is added to improve the toughness of the material? A cross-linking agent
What is added to prevent premature polymerization during storage? An inhibitor
What is the most commonly used inhibitor? Hydroquinone.
Cold cure or chemically activated......powder: Polymethylmethacrylate polymer
What is the cross-linking agent used in heat cured to improve the toughness of the material and help prevent craze lines? Glycol Dimethacrylate
What type of cured material uses a type of "pressure cooker?" heat cured
Steps in Addition Polymerization: 1. Initiation 2. Propagation 3. Termination
1. Initiation Begins the addition polymerization
2. Propagation Growth or lengthening of the monomer chain
3. Termination Termination of polymerization
Heat activated: Acrylic resins are typically activated with -------as the initiatior and ------- as the activator. benzoyl peroxide, heat
Light activated and dual cure composites are being introduced for temporary crowns and custom trays
Name one advantage and disadvantage of light activated and dual cured resins: advantage-stronger than acrylic disadvantage-price needs to come down
Example of an acrylic appliance: Orthodontic retainers
Teeth for dentures may be ------or----- acrylic or porcelain
Acrylic based soft liners for dentures are heat or cold cured
What is used to cover the tissue bearing aspect of a denture when a patient cannot tolerate the hard acrylic on their mucosa? denture liner
Tissue conditioners: What is used when the mucosa is so irritated that they have a hard time wearing the prosthesis? a temporary soft liner
--------------------------- loaded with plasticizers such as alcohol to make it soft. Polymethylmethacrylate polymer
What are some of the disadvantages of using materials that go through polymerization such as composites, dentures, and retainers? a high thermal coefficient of expansion, shrinkage occurs, they can irritate pulp
At home care of acrylic resin dentures: denture brush, non abrasive denture paste before placing in soak bath, calculus can be softened by a 1:1 solution of white vinegar and water, liquid soap can be used
Storage of acrylic resin dentures water to prevent warping, water while out during prophy, prosthesis with soft liner-NO mouthwash, alcohol has an adverse affect.
In office care of acrylic resin dentures: tartar and stain remover, can be gently scaled
Created by: karmstrong1
 

 



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