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Chem Exam 3

Chapters 4-5

QuestionAnswer
Thermochemistry Quantitative study of chem reactions involving the transfer of heat
2 Types of chem reactions Exothermic and Endothermic
2 Types of energy Potential and Kinetic
Potential Energy due to position ( stored)
Kinetic Energy due to motion
Chemistry Potential Energy breaking and making of chemical bonds
1st Law of thermodynamics total energy of universe remains constant (Energy can not be created or destroyed but transferred from one form to another)
7 forms of energy Mechanical, Radiant/Solar, Sound, Chemical, Heat, Electrical, Nuclear
Universe equation System + Surroundings
Exothermic Heat(q) exits or Work (w) done by the system
Endothermic Heat(q) enters or Work (w) is done on the system
3 types of systems Open, Closed, Isolated
State Functions properties that are determined by the state o the system, regardless of how the condition was achieved
4 examples of state function Energy, Pressure, Volume, Temperature
What is Temperature Measure of Hotness
Absolute Zero 0K Lowest Possible Temp
Change of 1 degree Celsius equals 1 K change
Heat always moves from hot (more energetic) to cold (less energetic)
Thermal Energy Joules or Cal energy associated with motion of particles
Heat Transfer of thermal energy from one place to another collision of particles
Thermal Energy depends on how much material you have
temp depends on average Kinetic Energy of the particles
Heat Capacity amount of heat required to raise the temp by one degree
Heat capacity is sample size dependent True
Specific Heat Capacity independents sample size
Calorimetry the experimental determination of heat flow
Specific heat with large volume takes longer to change heat
Q=m*c*^T M= mass in grams, c=Specific heat (J/K*G), ^T=change in temp (final- initial)
Thermochemical Equations where we deal with 1 mole of product ( reactant fractions)
^H change in enthalpy for the reaction that forms 1 mole of a substance from its elements in there standard states
Hess's Law if a reaction is carried out in a series of steps, ^H for the reaction equals sum of enthalpy changes
4 types of Physics Electricity, Magnetism, Radioactivity, Light
Frequency (v) number of waves per second
higher frequency equals higher energy
Visible light consists of electromagnetic waves
Electromagnetic Radiation the emission and transmission of energy in the form of electromagnetic waves
Electromagnetic Spectrum Gamma, X-ray, UV, Visible, Infrared, Microwaves, Radar, TV/Radio
Gamma rays (left) are Short and Fast with high energy
TV/Radio Waves are Long and Slow with Low energy
Visible Spectrum ROYGBIV backwards
Wavelength and frequency of radiant energy Inversely Related
Radiational Energy Proportional to frequency directly
Light Both a wave and a particle, result of an excited electron returning to a lower energy level
Heisenberg Uncertainty Principle define the energy of an electron exactly but accept limitation that we do not know the exact positions
Schrodinger's Wave Equation Describes energy of a given electron, probability of finding an electron in volume of space
n energy levels
l shape of orbital, volume of space that e- occupies
ml orientation off the orbital in space
l equals n-1
ml numbers plus or minus l and everything in-between
2 electrons in the same orbital they have sake n, l, ml, but deferent ms
Pauli Exclusion Principle no 2 electrons in an atom can have the same 4 quantum numbers
4 Quantum numbers n, l, ml, ms
d4 exception Cr, s level doesnt fill
d9 exception doesnt fill s level, Cu
Zn completely filled and nonmagnetic
the more unpaired the more magnetic
4 periodic trends Atomic Size, Ionic Size, Ionization Energy, Electron Affinity
where is the nucleus Center of XYZ coordinate
X-Ray Spectrosapy indirect measurement, diffraction pattern
Atomic Radius decreases left to right where left the biggest
Z*= Z-(number of core electrons)
Atomic Radius Increasing in size Top to Bottom where bottom the biggest
Cations Loose electrons and are smaller than neutral
Anions Gain electrons and are bigger than neutral
Ionization Energy minimum energy required to remove an electron from a gaseous atom in its grand state
ionization Energy formula I1 + X(g)=X+(g)+e-
what takes more energy takes more energy to move additional electrons
Electron Affinity reflects ability's of an atom to accept one or more electrons, energy charge that occurs when an electron is added to gaseous atom
Large negative electron affinity negatives ion is more stable
11 Gases H, N, O, F, He, Cl, Ar, Kr, Xe, Rn
2 liquids Hg, Br
Created by: brkolstoe
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