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Question | Answer |
---|---|
what does saturated mean? | carbons have as many attachements as possible |
hydrocarbon | C-C or C-H single bonds |
number of carbons or substituents: 1 | meth |
number of carbons or substituents: 2 | eth |
number of carbons or substituents: 3 | prop |
number of carbons or substituents: 6 | hex |
number of carbons or substituents: 4 | but |
number of carbons or substituents: 9 | non |
number of carbons or substituents: 11 | undec |
number of carbons or substituents: 12 | dodec |
if there are two chains of same length do you use the one with less or more substituents? | more |
what separates numbers from letters? | hyphen |
what separates two numbers? | commas |
-n- denotes: | normal linear chain |
when would cycloalkane not be used? | the freestanding chain is longer than the ring |
what is the order of the numbers for bicyclic compounds | descending |
dihedral or torsional angle | 60 degrees between two of the same groups |
which conformation has higher energy: staggered or ellipsed? | eclipsed |
cis | two groups on the same side of the ring |
trans | two groups on opposite sides of ring |
which is more stable: cis or trans | trans |
constitutional isomers: | compounds that have same molecular formula but different constitution |
stereoisomers: | same molecular formula and constitution but different arrangement of atoms |
enantiomers: | pair of non-superimposable mirror images |
R | clockwise |
S | counterclockwise |
specific rotation formula: | = a/ c x l where a = observed rotation, l= path length |
levorotary | - |
dextrorotary | + |
column chromatography | column packed with a polar solid and compounds passed through |
diastereomers: | stereoisomers that are not mirror images |
mesocompound | achiral and has a plane of symmetry |
in a fischer projection the horizontal lines are equivalent to: | wedges |
In a fischer projection the vertical lines equal: | dashes |
kinetics determines: | reaction rate |
thermodynamics determines: | where equilibrium lies |
intermediate | species formed during course of a reaction |
exothermic | transition state resembles reactants |
endothermic: | transition state resembles products |
how many r groups/ hydrogens does a secondary structure have | 2 R group 1 H |
how many r groups/ hydrogens does a primary structure have? | 1 r group/ 2 H |
how many r groups/ hydrogens does a tertialy structure have? | 3 r groups/ no hydrogens |
which is most stable? | tertiary |