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Orgo 2 test

QuestionAnswer
what does saturated mean? carbons have as many attachements as possible
hydrocarbon C-C or C-H single bonds
number of carbons or substituents: 1 meth
number of carbons or substituents: 2 eth
number of carbons or substituents: 3 prop
number of carbons or substituents: 6 hex
number of carbons or substituents: 4 but
number of carbons or substituents: 9 non
number of carbons or substituents: 11 undec
number of carbons or substituents: 12 dodec
if there are two chains of same length do you use the one with less or more substituents? more
what separates numbers from letters? hyphen
what separates two numbers? commas
-n- denotes: normal linear chain
when would cycloalkane not be used? the freestanding chain is longer than the ring
what is the order of the numbers for bicyclic compounds descending
dihedral or torsional angle 60 degrees between two of the same groups
which conformation has higher energy: staggered or ellipsed? eclipsed
cis two groups on the same side of the ring
trans two groups on opposite sides of ring
which is more stable: cis or trans trans
constitutional isomers: compounds that have same molecular formula but different constitution
stereoisomers: same molecular formula and constitution but different arrangement of atoms
enantiomers: pair of non-superimposable mirror images
R clockwise
S counterclockwise
specific rotation formula: = a/ c x l where a = observed rotation, l= path length
levorotary -
dextrorotary +
column chromatography column packed with a polar solid and compounds passed through
diastereomers: stereoisomers that are not mirror images
mesocompound achiral and has a plane of symmetry
in a fischer projection the horizontal lines are equivalent to: wedges
In a fischer projection the vertical lines equal: dashes
kinetics determines: reaction rate
thermodynamics determines: where equilibrium lies
intermediate species formed during course of a reaction
exothermic transition state resembles reactants
endothermic: transition state resembles products
how many r groups/ hydrogens does a secondary structure have 2 R group 1 H
how many r groups/ hydrogens does a primary structure have? 1 r group/ 2 H
how many r groups/ hydrogens does a tertialy structure have? 3 r groups/ no hydrogens
which is most stable? tertiary
Created by: Lyd543
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