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Chem Test 3

QuestionAnswer
Energy of one photon equation (v) E=hv
Energy of one photon equation E=hc/λ
Speed of light equation c=λv
Planck's constant 6.63*10^-34
Photoelectric Effect When electromagnetic radiation or light hits a metal at a high frequency and electrons are ejected from the surface of the metal. Einstein explained by saying light is a quanta of energy that are like particles (photons). ^ frequency of light = faster e^-
Light as a wave Waves of electromagnetic radiation. Light can be reflected, refracted, and diffracted.
Light as a particle Photoelectric effect, electromagnetic energy comes in packets/quanta called photons which is proportional to frequency bc the higher the frequency the faster the electron and the shorter the wavelength the more e^- ejected.
Difference between light as a wave and light as a particle The wave nature of light states that light can behave as an electromagnetic wave, whereas the particle nature of light states that light consists of particles called photons.
Bohr Model Using the structure of a solar system, Niels Bohr created an inaccurate model of an atom called the planetary model or Bohr model that shows fixed electrons revolving around a dense nucleus.
Quantum Model A model of an atom made by Erwin Schrodinger that is the modern understanding of an atom. This uses atomic orbitals to explain the uncertain locations of electrons in the atom.
Differences between Bohr Model and Quantum Model B: electrons behave as particles, Q: the electron has both particle and wave behavior. B: e^-s are in fixed locations, Q: e^-s have indefinite location in the electron cloud. B: can only be applied to the hydrogen atom, Q: can be applied to all atoms
Similarities between Bohr and Quantum Models Both explain the structure of an atom, both consider a heavily charged nucleus and electrons revolving around it.
Heisenberg Uncertainty Principle It is impossible to know both the velocity or momentum and the position of a particle, such as a photon or electron, at the same time. Doesn't apply for ordinary sized objects.
First Quantum Number Principle QN: "n" is an integer that describes the energy level of an e^-. n=0,1,2,3,4...; first # in electron config.
Second Quantum Number Angular QN: "l" describes the shape of a sublevel within an energy level (type of orbital). s sublevel: sphere l=0; p sublevel: peanut/dumbbell l=1; d sublevel: double peanut/two dumbbells l=2; f sublevel: flower l=3. 1st letter in electron config.
Third Quantum Number Magnetic QN: describes the orientation of the orbital within a sublevel, -l<ml<l; count to the 2nd # in electron config following the 3 guiding principles.
Fourth Quantum Number Electron Spin: ms=+-1/2
Aufbau Principle electrons occupy the lowest energy orbital first, then move to the next. first fill 1s, then 2s, then 2p, then 3s...
Pauli Exclusion Principle Spin in one orbital must be different: up down not up up or down down. no two electrons can have the same 4 electronic quantum #s.
Hund's Rule single before double, all singles have the same spin
Principle Number of Electrons
Order of spdf
Relationship between frequency and wavelength
Relationship between energy and wavelength
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