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Physics Ch. 13-15

Temperature and Kinetic Theory

TermDefinition
temperature the measure of how hot or cold a system is
heat the energy which is transferred between 2 systems that are at different temperatures
thermal contact when 2 systems can exchange energy via heat transfer
thermal equilibrium when 2 systems are at the same temperature
Fahrenheit to Celsius 5/9(T - 32)
absolute zero zero on the Kelvin scale
ideal gas law PV = nRT
Boltzmann's consant K = 1.381*10^-23 J/K
universal gas constant R = 8.134 J/(mol*K)
degrees of freedom ways that a diatomic molecule can move - there are 5
latent heat the heat needed to change the phase of one kg of a substance
latent heat of fusion Lf used when a solid changes to a liquid
latent heat of vaporization Lv used when a liquid changes to a gas
positive Q when heat is transferred to a system
negative Q when heat is transferred from
convection the transfer of heat due to the movement or circulation of material - natural or forced circulation
radiation the transfer of energy without a medium
quasi-static thermodynamic processes with slow changes between equilibrium states - they are reversible
isobaric processes keep pressure constant
isochoric processes keep volume constant
isothermal processes keep temperature constant
adiabatic (isentropic) processes allow no heat transfer
1st law of thermodynamics the internal energy U of a system is a measure of the total energy inside the system - a restatement of energy conservation
2nd law of thermodynamics heat spontaneously flows from a hot system to a cold one - Clausius statement
heat engine a system that undergoes a series of thermodynamic processes that form a complete cycle (closed loop on a P-V diagram)
Carnot cycle consists of 4 steps: isothermal expansion, adiabatic expansion, isothermal compression, and adiabatic compression - the most efficient engine possible
refrigerator a heat engine ran in reverse - work is done on the system to force the heat to flow into the hot resevoir
Carnot refrigerator the reverse cycle of a Carnot engine - the most efficient refrigerator possible
entropy a state variable (only changes matter), delta S = Q/T
Created by: imr36093
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