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Physics Ch. 13-15
Temperature and Kinetic Theory
Term | Definition |
---|---|
temperature | the measure of how hot or cold a system is |
heat | the energy which is transferred between 2 systems that are at different temperatures |
thermal contact | when 2 systems can exchange energy via heat transfer |
thermal equilibrium | when 2 systems are at the same temperature |
Fahrenheit to Celsius | 5/9(T - 32) |
absolute zero | zero on the Kelvin scale |
ideal gas law | PV = nRT |
Boltzmann's consant | K = 1.381*10^-23 J/K |
universal gas constant | R = 8.134 J/(mol*K) |
degrees of freedom | ways that a diatomic molecule can move - there are 5 |
latent heat | the heat needed to change the phase of one kg of a substance |
latent heat of fusion Lf | used when a solid changes to a liquid |
latent heat of vaporization Lv | used when a liquid changes to a gas |
positive Q | when heat is transferred to a system |
negative Q | when heat is transferred from |
convection | the transfer of heat due to the movement or circulation of material - natural or forced circulation |
radiation | the transfer of energy without a medium |
quasi-static | thermodynamic processes with slow changes between equilibrium states - they are reversible |
isobaric processes | keep pressure constant |
isochoric processes | keep volume constant |
isothermal processes | keep temperature constant |
adiabatic (isentropic) processes | allow no heat transfer |
1st law of thermodynamics | the internal energy U of a system is a measure of the total energy inside the system - a restatement of energy conservation |
2nd law of thermodynamics | heat spontaneously flows from a hot system to a cold one - Clausius statement |
heat engine | a system that undergoes a series of thermodynamic processes that form a complete cycle (closed loop on a P-V diagram) |
Carnot cycle | consists of 4 steps: isothermal expansion, adiabatic expansion, isothermal compression, and adiabatic compression - the most efficient engine possible |
refrigerator | a heat engine ran in reverse - work is done on the system to force the heat to flow into the hot resevoir |
Carnot refrigerator | the reverse cycle of a Carnot engine - the most efficient refrigerator possible |
entropy | a state variable (only changes matter), delta S = Q/T |