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Chem: Exam 4
Carbohydrates, Lipids, and Proteins
Question | Answer |
---|---|
study of chemical substances found in living organisms? | biochemistry |
chemical substances found in living organisms? | biochemical substances |
molecules of life include:? | carbohydrates, lips, proteins, DNA and RNA |
carbon with 4 different groups attached? | chiral carbon |
what reacts to form acetals? | aldehydes and alcohols, ketones and alcohols |
glucose molecules linked via alpha (1->4) and alpha (1->6) linkages? | amylopectin |
'animal starch' ; glucose molecules linked via alpha (1->4) and alpha (1->6) linkages | glycogen |
glucose linked via beta (1->4) linkages | cellulose |
n-acetyl amino glucose linked via beta (1->4) linkages | chitin |
an organic molecule that is insoluble in water but soluble in nonpolar solvents ; waxy, greasy, oily | lipid |
straight-chain carboxylic acid with an even number of carbon atoms ; can be saturated or unsaturated | fatty acid |
one c=c bond | monounsaturated |
more than one c=c bond | polyunsaturated |
needed by the body but not synthesized within the body | essential fatty acid |
essential fatty acids that are used to produce substances that regulate blood clotting, immune response, and blood pressure | linoleic acid and linolenic acid |
triacylglycerol that is solid at room temperature | fat |
triacyglycerol that is liquid at room temperature | oil |
hydrogenation of fats or oils results in what? | lowers degree of saturation --> increases MP |
what can partial hydrogenation lead to? | trans fats |
unsaturated fatty acids are _____ in air to form short chain _______ __ | oxidized ; carboxylic acids |
compound containing four fused rings | steroid |
component of cell membranes, precursors for bile salts, vitamin d, the adrenocorticoid hormones, and many sex hormones | steroids |
important for lipid digestion in the instestines | steroids |
amino acids that cannot easily be synthesized within the body but must be obtained in the diet | essential amino acids |
what is chiral in all amino acids, except glycine | alpha-carbon |
basic? | amine |
acidic? | carboxyl |
the amine is positively charged while the carboxylate is negatively charged when the pH is where? | 7 |
short chains of amino acids - shorter than 50 | peptides |
long chains of amino acids - longer than 50 | proteins |
order in which amino acids are linked together | primary structure of proteins |
attractive forces between amino acids accounts for? | 3D shape of protein |
breaking the amide bond into smaller peptides or amino acids | hydrolysis |
loss of native state, often associated with loss of protein activity | denaturation |
biological catalysts ; most are proteins | enzymes |
properties of enzymatic reactions | - increase reaction rates up to 10000000 fold |
reactant molecule | substrate |
uniquely shaped surface where substrate binds | active site |
substrate does not fit into active site, protein conforms to shape of substrate | induced-fit model |
non-protein component of enzyme | cofactor |
enzyme that cleaves an HIV polyprotein to form reverse transcriptase, integrase, etc. | HIV protease |
inhibits HIV protease enzyme by binding the active site ; used to treat AIDS | protease inhibitor |