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Min Test 1

QuestionAnswer
Diamond - Native Element C
Graphite - Native Element C
Pyrite - Sulfide FeS2
Chalcopyrite - Sulfide CuFeS2
Galena - Sulfide PbS
Sphalerite - Sulfide ZnS
Hematite - Oxide Fe2O3
Magnetite - Oxide Fe3O4
Corundum - Oxide Al2O3
Ilmenite - Oxide FeTiO3
Rutile - Oxide TiO2
Halite - Halide NaCl
Fluorite - Halide CaF2
Calcite - Carbonate CaCO3
Aragonite - Carbonate CaCO3
Siderite - Carbonate FeCO3
Dolomite - Carbonate CaMg(CO3)2
What is a mineral? a naturally occurring crystalline solid with a definite, but not necessarily fixed, chemical composition
What is a crystalline solid? repeating crystal structure, dictated by cations and anions
Why do we have so few minerals (compared to animal species)? they’re fundamental building blocks. there are a finite number of ways in which cations and anions can combine in order to form minerals
How do we know about the chemical composition of the earth? Composition of the Sun, Composition of chondrites, Clues from seismology
What is the relative composition of crust? • Oxygen 46% • Silicon 28% • Aluminum 8% • Iron 5% • Calcium 4%
What are the most common minerals in the Earth’s crust? • Plagioclase feldspar • Quartz • K-feldspar • Pyroxene • Mica • Amphibole • Clay • Olivine
What are the major crustal elements? -O -Si -Al -Fe -Ca -Na -K -Mg
What are the siderophile (iron-loving) elements? • Fe Co Ni • Ru Rh Pd • Re Os Ir Pt Au • Mo Ge Sn C P • (Pb) (As) (W)
What are the chalcophone (sulfur-loving) elements? • Cu Ag (Au) • Zn Cd Hg • Ga In Tl • (Ge) (Sn) Pb • As Ab Bi • S Se Te • (Fe) (Mo) (Re)
What are the lithophile (crust-loving?) elements? • Li Na K Rb Cs • Be Mg Ca Sr Ba • B Al Sc Y REE • (C) Si Ti Zr Hf Th • (P) V Nb Ta • O Cr W U • (Fe) Mn • F Cl Br I • (H) (Tl) (Ga) (Ge) (N)
Common cations (lose electrons, positive charge) include... H, Li, C, N, Na, Mg, P
Common anions (gain electrons, negative charge) include... O, F, S, Cl,
Properties of Ionic bonding include... • electron transfer • one gets a positive charge, one gets a negative charge, they’re attracted to one another • medium to hard • high symmetry • fully to partially transparent • highly water soluble
Properties of Covalent bonding include... • electron sharing • very hard • high melting temperature • low symmetry • brittle, often break by conchoidal fracture
Properties of Metallic bonding include... • electrons aren’t linked, free to move • this is why they’re good conductors • not water soluble • variable hardness and breaking • highly symmetrical and opaque
Properties of Hydrogen bonding include... • fairly weak bond • has to do with polarity
Properties of Van der Waals bonding include... • at any given moment, there may be a positive charge on one side and a negative charge on the other side • one of the weakest bonds, between sheets
Common Cation charges • Si 4+ • Ti 4+ • Al 3+ • Fe 2+,3+ o Ferrous 2+ o Ferric 3+ • Mg 2+ • Mn 2+ • Ca 2+ • Na 1+ • K 1+ • P 5+
Common Anion charges • O 2- • S 2- • (OH) 1- o (ClH)- o (FH)-
Coordination the number of nearest neighbors (ions in contact) to any ion
What is the formula for radius ratio? radius of cation/radius of anion
What factors affect atomic radius? Increase in charge (decreases radius), Increase in coordination (increases radius), Increase in temperature (increases radius), Increase in atomic number (decreases radius, unless you are also adding shells)
How do we think we know elemental abundances? • taking samples • analyzing glacial lakes (mechanical weathering) • analyzing loess (windblown sediment) • research literature
How did Goldschmidt come up with his classification scheme? siderophile, chalcophile, lithophile, atmophile. Based on greeks?
How are minerals classified? chemical composition & anion group
What are the types of packing? hexagonal closest packing, cubic closest packing
How do you calculate bond strength? charge/coordination #
Cubic closest packing examples tetrahedral or octahedral
How do you figure out coordination number? NaCl: each Na surrounded by 6 Cl (CN=6)
Hexagonal closest packing ABABABABABABAB stacking Arrangement of equal size spheres
Cubic closest packing ABCABCABCABCABCABC stacking
Types of insterstitial holes? o Trigonal hole o Tetrahedral hole o Octahedral hole
Pauling's rule 1 • a coordination polyhedron of anions is formed about each cation, the cation-anion distance being determined by the radius sum and the coordination number of the cation by the radius ratio
Pauling's rule 2 • The electrostatic valency principle, or bond strength – in a stable crystal structure, the total strength of the valency bonds that reach an anion from all the neighboring cations is equal to the charge of the anion
Pauling's rule 3 • The existence of edges, and particularly of faces, common to two anion polyhedra in a coordinated structure reduces its stability
Pauling's rule 4.1 • In a crystal containing different cations, those of high valency and small coordination tend not to share polyhedral elements with each other, and when they do,
Pauling's rule 4.2 the shared edges contract (to put more negative charge between the cations), and the cations are displaced from their polyhedral centers, away from the shared edge or face
The principle of parsimony the number of essentially different kinds of constituents in a crystal tends to be small, because, characteristically there are only a few types of contrasting cation and anion sites
Isodesmic all the bond strengths are the same (halite)
anisodesmic all the bond strengths are not uniform (carbonates, sulfates)
mesodesmic the bond strength between the cation and the anion equals exactly half of the charge of the…?
Siderophile metallic (core)
Chalcophile sulfide (core and sulfide ore deposits)
Lithophile silicates and oxides (crust and mantle)
Created by: haleyBUGoxox
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