carboxylic acid altern
Help!
|
|
||||
|---|---|---|---|---|---|
| acyl halide | OH replaced by X
🗑
|
||||
| anhydride | OH replaced by OCOR
🗑
|
||||
| amide | Oh replaced by NH2
🗑
|
||||
| ester | OH replaced by OR
🗑
|
||||
| naming acyl haldes | change "ic acid" "yl acid"
🗑
|
||||
| Carboxylic acid + thionyl Chloride (SOCl2)or PCL3 or PBr3 | acyl chloride
🗑
|
||||
| acyl chloride + h2O | forms back carboxylic acid
🗑
|
||||
| acyl chlroide + alcohol (ROH) | forms ester R-C=O
\OR
🗑
|
||||
| acyl chlorides + ammonia (NH3) | forms amide R-C=O
\NH2
🗑
|
||||
| aromatic substitution | Friedel craft acylation
🗑
|
||||
| wats friedel craft | aromatic + acid chloride with AlCl3
🗑
|
||||
| results of friedel craft | benzene-R-C=O
\R
🗑
|
||||
| acid halide + H2 in Pd/BaSO4 (quinoline) | halide replaced by H
🗑
|
||||
| anhydride | without water; 2 acid bonding and removing water
🗑
|
||||
| gen form for anhydride | R-C=O
\O-C=O
\R
🗑
|
||||
| acid chloride + carboxylate salt ( R-C=O \O- | halide is lost and anhydride formed
🗑
|
||||
| dioic acid + heat | cyclic anhydride
🗑
|
||||
| anhydrydes + water | 2 carboxylic acids
- molecule splie adding OH to one and H to O
🗑
|
||||
| ammonia (NH3) + anhydride | mol splits forming carboxylate attached to NH4
-forms amide
🗑
|
||||
| anhydride + alcohol | mol splits and adds RO from alcohol to one and H to the O in the second
- ester + carboxylic acid
🗑
|
||||
| anhydride + benzene in friedel craft( AlCl3) | splits anhydride and attaches R-C=O to benzene + carboxylate
🗑
|
||||
| amide gen formula | R-C=O
\NR2
🗑
|
||||
| formation of amide | acid chlorides with amine (prim n sec)
or anhydride with ammonia
🗑
|
||||
| amide+ H2O in acid | NR2 replaced by OH to form carboxylic acid
🗑
|
||||
| hoffman rearrangement (BrO-) | amide to primary amine ( loses carbonyl)
🗑
|
||||
| BrO- + amide | H2NR ( primary amine); Hoffman rerarrangement
🗑
|
||||
| amide + LAH | loses =O to form amine
🗑
|
||||
| gen formula for ester | RC=O
\OR
🗑
|
||||
| synthesis of ester | acid + alcohol
🗑
|
||||
| naming ester | alkyl alkanoates
🗑
|
||||
| ester + h2o | H adds to =O forming OH and H adds to the other O splitting the ester
- carboxylic acid and alcohol
🗑
|
||||
| ester + ammonia | adds H to O splitting the ester NH2 adds to carbonyl section
- amide + alcohol
🗑
|
||||
| ester + alcohol | displaces the OR by adding H and adds the alcohols OR to the C=O grp
- new ester + alcohol ( transesterification)
🗑
|
||||
| Grignard reagent (RMgBr) + ester | OR is replaced by the R grp - forms ketone
🗑
|
||||
| LAH + ester | - removes =O and adds H to the other O
prim alcohol
🗑
|
||||
| ester + NaBH4 | doesnt produce prim alchols
🗑
|
Review the information in the table. When you are ready to quiz yourself you can hide individual columns or the entire table. Then you can click on the empty cells to reveal the answer. Try to recall what will be displayed before clicking the empty cell.
To hide a column, click on the column name.
To hide the entire table, click on the "Hide All" button.
You may also shuffle the rows of the table by clicking on the "Shuffle" button.
Or sort by any of the columns using the down arrow next to any column heading.
If you know all the data on any row, you can temporarily remove it by tapping the trash can to the right of the row.
To hide a column, click on the column name.
To hide the entire table, click on the "Hide All" button.
You may also shuffle the rows of the table by clicking on the "Shuffle" button.
Or sort by any of the columns using the down arrow next to any column heading.
If you know all the data on any row, you can temporarily remove it by tapping the trash can to the right of the row.
Embed Code - If you would like this activity on your web page, copy the script below and paste it into your web page.
Normal Size Small Size show me how
Normal Size Small Size show me how
Created by:
smuttz
Popular DAT sets